Scharnhauser公园学校和体育馆,奥斯特菲尔登

这个综合学校包括一个主建筑,一个体育馆和各种户外设施,朝向一片处在前军事基地上的住宅开发区。整个主建筑沿纵向被一个由顶部采光的回廊从中间分开,由此可以进入两侧的教室,回廊局部变宽的部分构成一个公共空间。这个构想与将城市设计理论运用于建筑内部设计的概念相符合:街道、广场和建筑被看成了建筑内部空间部分。虽然这个建筑从外部看来是个大体块,但内部空间却设计流畅,通道有的通向楼层的各个角落,也有的依着倾斜的地势因势而建。由墙面反射的散射光线加强了内部空间的肃穆和厚重感。在具有宗教感的整体风格下,整个学校的设计和装饰也显得古香古色,如一部宽阔的观光楼梯、两个塔形和壁炉形的建筑构成元素等。不同历史风格建筑的叠加给这个校区带来一种复杂的味道,堪比阿尔多·罗西(Aldo Rossi)的设计或泰辛(Tessin)新理性主义的代表作。     

The effect of pack-aluminisation on the microstructure of MCrAlY and the performance of thermal barrier coatings

Plasma spraying and pack-aluminising processes were combined and applied to the nickel-base superalloy Mar-M247 to improve its cyclic oxidation resistance. The performance tests of duplex ZrO₂-8 wt.%Y₂O₃/MCrAlY thermal barrier coatings (TBCs) were conducted at 1050 °C, 1075 °C, 1100 °C, 1150 °C and 1200 °C. The results of the experiments in this study showed that TBC specimens with the aluminised MCrAlY bond coat exhibited higher cyclic lives (except for the Ni-22Cr-10Al-1Y bond coat), at all the temperatures tested, than specimens on which the bond coat was not aluminised. The microstructures of the Co-29Cr-6Al-1Y, Co-32Ni-21Cr-8Al-0.5Y and Ni-22Cr-10Al-1Y bond coats with or without aluminising treatment were examined in detail using a scanning electron microscope equipped with an electron probe microanalyzer.     

Photoinduced bidirectional phase transitions in single crystals of polydiacetylenes

Photoinduced phase transitions have been observed between the two phases in single crystals of polydiacetylenes with side-groups of alkylurethanes. The threshold of the excitation intensity for the photochromism is extremely low, one absorbed photon per 140 repeated backbone units, indicating a collective nature of the photoconversion. The excitation spectra for the converted fraction clearly show that the photoinduced phase transition is mediated by photogeneration of polaronic species and not of singlet excitons.     

Chiroptical activity of holmium pyrogermanate: tetragonal Ho2Ge2O7

Chiroptical luminescence and circular dichroism measurements are reported for single crystals of Ho₂Ge₂O₇. These crystals belong to the tetragonal space group P4,2,2 (or P4₃2₁2) with Z=4. Each Ho³⁺ ion in the crystal structure is coordinated to seven oxygens to form a distorted pentagonal bipyramid. The Ho³⁺ ions exhibit luminescence from several excited multiplet levels; chiroptical luminescence spectra are reported for ⁶I₈ → ⁶F₆, ⁶S₂, and ⁶F₃ at a sample temperature of 10 K. Room-temperature absorption and circular dichroism measurements are reported for the ⁶I₈ → ⁶F₆, ⁵S₂, ⁶F₄, and ⁶F₃ transition regions.     

Analysis of the fluorescence of the ion Eu in fluoroborate glasses containing silver particles

We have studied theoretically and experimentally the fluorescence enhancement in fluoroborate glasses, doped with the ion Eu³⁺, containing small silver particles. The model developed shows that the gain coefficient has quenching and enhancement regions. The absorption peak of the metallic particles occurs at 425 nm, which is not in resonance with the ⁵L₆ level of the ion Eu³⁺. For this reason it is not possible to make a complete comparison between theoretical and experimental results, but the structure of the absorption spectra allows us to check some crucial aspects of the problem, such as energy transfer, enhancement of the local field and the high absorption by the particle system. Results of electronic microscopy have revealed non-uniformity of the particle distribution with average radii of approximately 20 Å and 35 Å and a measured localized mean filling factor of 0.02.     

Catalytic behaviour and surface properties of supported lanthana

This paper deals with the role of dispersed lanthana as an active phase in several catalytic reactions: CO hydrogenation, CO oxidation, and oxidative dimerization of methane.

Characterization of the prepared catalysts indicates that lanthana can be effectively dispersed on silica and on ceria. While in the case of silica-supported catalysts lanthana appears at the surface, leading to an almost full coverage for loadings higher than 40%, in the case of ceria-based systems, lanthana forms a solid solution with the support.

In all the reactions studied, the presence of lanthana can be related to significant changes in the catalytic properties of the bare supports. Thus, the selectivity towards the total oxidation products observed on pure ceria is decreased, and the low activity shown by silica is enhanced. For the CO+H₂ reaction, the addition of lanthana also generates upgraded products.     

The electronic structure of organometallic complexes of the f elements XXVIII: Interpretation of the optical and magnetochemical data of a cyclohexylisocyanide adduct derived from Tris(η-cyclopentadienyl)samarium(III)

The absorption spectrum of Cp₃Sm·CNC₆H₁₁ has been measured at room temperature and at low temperatures in a hydrocarbon glass and in a KBr pellet. Electron paramagnetic resonance and magnetic susceptibility measurements are also reported in this paper. The observed optical bands were assigned on the basis of calculations which assumed that the crystal field parameters of the samarium complex were the same as for the previously analyzed Cp₃Pr·CNC₆H₁₃. The parameters of an empirical Hamiltonian were fitted to the energies of 39 levels to give an r.m.s. deviation of 21 cm⁻. On the basis of the wavefunctions of the crystal field ground state obtained from the fit, the ground state g values and the temperature-dependent magnetic susceptibility were calculated and compared with the experimental values.     

A sequential linear programming approach to solve mixed integer programming problems

The optimal operation of pumps in a large water supply system under time-of-use electricity rates is formulated as a mixed integer programming (MIP) problem. The problem is solved using an iterative linear programming (LP) scheme. The scheme is applied to an actual world problem, the City of Inglewood Water Supply System. Computational results are presented and termination criteria for the solution scheme are discussed.     

A basis for the design of a multiattribute heuristic for single resource project scheduling

Two important characteristics of a project network are the network's topology and the amount of resources available. Most published project scheduling procedures take one or both of these two characteristics into account. Project scheduling procedures that are robust over variations of network characteristics are desirable. The degree of robustness is generally gauged by one or more measures of performance.

The objective of this paper is to compare a set of priority rules that are useful for a single resource project scheduling problem. The set of networks suggested by Patterson (1973) is used along with the set of performance measures proposed by Khattab and Choobineh 1991. The result of this comparison allows one to design a multiattribute heuristic for a single resource project scheduling problem.